(E)-3-(2-Chloro-3,3,3-trifluoroprop-1-enyl)-2,2-dimethyl-N-(2-naphthyl)cyclopropanecarboxamide
نویسندگان
چکیده
منابع مشابه
(E)-3-(2-Chloro-3,3,3-trifluoroprop-1-enyl)-2,2-dimethyl-N-(2-naphthyl)cyclopropanecarboxamide
The title compound, C(19)H(17)ClF(3)NO, was synthesized from 3-[(E)-2-chloro-3,3,3-trifluoro-prop-1-en-yl]-2,2-dimethyl-cyclopropane-carboxylic acid and 2-aminona-phthalene. There are two molecules in the asymmetric unit. The dihedral angle between the naphthalene and cyclo-propane units is 111.6 (5)°. Molecules are connected into chains by intermol-ecular N-H⋯O hydrogen bonds. One of the Cl at...
متن کامل(E)-3-(2-Chloro-3,3,3-trifluoroprop-1-enyl)-2,2-dimethyl-N,N-diphenylcyclopropanecarboxamide
The title compound, C(21)H(19)ClF(3)NO, was synthesized from 3-[(E)-2-chloro-3,3,3-trifluoro-prop-1-en-yl]-2,2-dimethyl-cyclo-propane-carboxylic acid and diphenyl-amine. The propenyl and carboxamide substituents lie on the same side of the cyclo-propane ring plane, with the two methyl substituents on either side of the plane. The phenyl rings of the carboxamide are inclined at an angle of 84.6 ...
متن کامل(E)-3-(2-Chloro-3,3,3-trifluoroprop-1-enyl)-2,2-dimethyl-N-p-tolylcyclopropanecarboxamide
There are two mol-ecules in the asymmetric unit of the title compound, C(16)H(17)ClF(3)NO. The benzene ring in each mol-ecule makes a dihedral angle of 66.6 (3)° [116.3 (4)° in the second mol-ecule] with the plane of the cyclo-propane ring. The F atoms of the CF(3) groups are disordered equally over two positions. The amide hydrogen is linked with the amide oxygen in another mol-ecule by an int...
متن کامل(E)-3-Chloro-N-[(2-ethoxynaphthalen-1-yl)methylidene]aniline
In the title compound, C(19)H(16)ClNO, the dihedral angle between the naphthalene ring system and the chloro-benzene ring is 61.90 (10)° and the C-N-C-C torsion angle is 174.6 (2)°. The mol-ecular structure is stabilized by an intra-molecular C-H⋯N hydrogen bond. The crystal structure features π-π stacking inter-actions [centroid-centroid distances = 3.7325 (17) and 3.8150 (17) Å].
متن کامل3-(2-Chloro-3,3,3-trifluoroprop-1-en-1-yl)-2,2-dimethyl-N-[3-(trifluoromethyl)phenyl]cyclopropanecarboxamide
In the title mol-ecule, C(16)H(14)ClF(6)NO, the cyclo-propane ring forms a dihedral angle of 70.82 (18)° with the benzene ring. The torsion angles about the ethyl-ene and amide bonds are -2.2 (5) (Cl-C-C-C) and 0.8 (5)° (O-C-N-C). A supra-molecular chain propagated by glide symmetry along [001] and mediated by N-H⋯O hydrogen bonds is observed in the crystal packing.
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2008
ISSN: 1600-5368
DOI: 10.1107/s1600536808032078